| 2013-09-21 | Genoa CFC | 0-0 | Livorno |
| 2013-09-21 | AC Chievo Verona | 2-1 | Udinese Calcio |
| 2013-09-21 | US Cagliari | 2-2 | UC Sampdoria |
| 2013-09-22 | AC Milan | 1-2 | SSC Napoli |
| 2013-09-22 | AS Roma | 2-0 | SS Lazio |
| 2013-09-22 | FC Juventus | 2-1 | Hellas Verona |
| 2013-09-22 | Catania | 0-0 | Parma AC |
| 2013-09-22 | Bologna FC | 1-2 | Torino |
| 2013-09-22 | Atalanta BC | 0-2 | AC Fiorentina |
| 2013-09-22 | Sassuolo Calcio | 0-7 | FC Internazionale |
| Home | 3 |
| Draw | 3 |
| Away | 4 |
| Under | 4 |
| Over | 6 |
| Pos | Team | M. | W | D | L | GF | GA | Pts |
|---|---|---|---|---|---|---|---|---|
| 1 | AS Roma | 4 | 4 | 0 | 0 | 10 | 1 | 12 |
| 2 | SSC Napoli | 4 | 4 | 0 | 0 | 11 | 3 | 12 |
| 3 | FC Internazionale | 4 | 3 | 1 | 0 | 13 | 1 | 10 |
| 4 | AC Fiorentina | 4 | 3 | 1 | 0 | 10 | 4 | 10 |
| 5 | FC Juventus | 4 | 3 | 1 | 0 | 8 | 3 | 10 |
| 6 | Livorno | 4 | 2 | 1 | 1 | 6 | 3 | 7 |
| 7 | Torino | 4 | 2 | 1 | 1 | 6 | 5 | 7 |
| 8 | SS Lazio | 4 | 2 | 0 | 2 | 6 | 7 | 6 |
| 9 | Hellas Verona | 4 | 2 | 0 | 2 | 5 | 6 | 6 |
| 10 | US Cagliari | 4 | 1 | 2 | 1 | 6 | 7 | 5 |
| 11 | AC Milan | 4 | 1 | 1 | 2 | 7 | 7 | 4 |
| 12 | Udinese Calcio | 4 | 1 | 1 | 2 | 6 | 6 | 4 |
| 13 | Genoa CFC | 4 | 1 | 1 | 2 | 5 | 7 | 4 |
| 14 | AC Chievo Verona | 4 | 1 | 1 | 2 | 4 | 8 | 4 |
| 15 | Atalanta BC | 4 | 1 | 0 | 3 | 3 | 6 | 3 |
| 16 | UC Sampdoria | 4 | 0 | 2 | 2 | 4 | 8 | 2 |
| 17 | Bologna FC | 4 | 0 | 2 | 2 | 4 | 8 | 2 |
| 18 | Parma AC | 4 | 0 | 2 | 2 | 2 | 6 | 2 |
| 19 | Catania | 4 | 0 | 1 | 3 | 1 | 7 | 1 |
| 20 | Sassuolo Calcio | 4 | 0 | 0 | 4 | 1 | 15 | 0 |
